A novel concept and design for highly efficient photoelectrocatalytic materials with high performance, stability, and charge transport properties: development of an innovative next-generation green technology.

In semiconductors, generating charges via catalysis is a highly challenging task and characteristic of heterojunction photoanodes. A dithiophene-4,8-dione spin-coated film layer has a positive effect on the holes (positive charge carriers) for a long time in BHJ films in the solid state of materials. The photoexcited holes created in the BHJ film can persist for long periods of time, which is beneficial for catalytic reactions. In this study, a photoanode is electrically coupled to a hydrogen gas-evolving platinum cathode. When the photoanode is electrically coupled to a H2 gas evolving Pt cathode, curiously long-lived hole polaron states are observed on the timescale of seconds under operational conditions. These long-lived holes play a crucial role in enhancing the hydrogen peroxide oxidation performance of the film overlayer spin-coated onto the photoanode. The spin-coated film overlayer on the photoanode achieves the best oxidation performance for hydrogen peroxide of approximately 6.5 mA cm-2 at 1.23 VRHE without the need of a catalyst. This demonstrates the effectiveness of the overlayer in improving the catalytic performance of the photoanode with a better efficiency of 17.5% when using 851 nm excitation. This indicates that a relatively high percentage of incident photons at that specific wavelength is converted into photocurrent by the photoanode. This approach can lead to more efficient oxidation catalysis as demonstrated in the case of hydrogen peroxide oxidation.

TiO2/ZnO Nanocomposite Material for Efficient Degradation of Methylene Blue.

In this research work, we have produced a composite material consisting titanium dioxide (TiO2) and zinc oxide (ZnO) nanostructures via precipitation method. Scanning electron microscopy (SEM) study has shown the mixture of nanostructures consisting nanorods and nano flower. Energy dispersive spectroscopy (EDS) study has confirmed the presence of Ti, Zn and O as main elements in the composite. X-ray diffraction (XRD) study has revealed that the successful presence of TiO2 and ZnO in the composite. The composite material exhibits small optical energy band gap which led to reduction of the charge recombination rate of electron-hole pairs. The band gap for the composite TiO2/ZnO samples namely 1, 2, 3 and 4 is 3.18, 3.00, 2.97 and 2.83 eV respectively. Small optical bandgap gives less relaxation time for the recombination of electron and hole pairs, thus favorable photodegradation is found. The degradation efficiency for the TiO2/ZnO samples for methylene blue in order of 55.03%, 75.7%, 85.14% and 90.08% is found for the samples 1, 2, 3 and 4 respectively. The proposed study of titanium dioxide addition into ZnO is facile and inexpensive for the development of efficient photocatalysts. This can be capitalized at large scale for the energy and.

Tin as an Effective Doping Agent into ZnO for the Improved Photodegradation of Rhodamine B.

We have fabricated ZnO nano rods by hydrothermal method and successively doped them with tin (Sn) using different concentrations of 25, 50, 75 and 100 mg of tin chloride. XRD of the fabricated structures showed that ZnO possess hexagonal wurtzite phase. Scanning electron microscopy (SEM) was used to explore the morphology and it shows nanorod like morphology for all samples and no considerable change in the structural features were found. The dimension of nanorod is 200 to 300 nm. The doped materials were then investigated for their photo catalytic degradation of environmental pollutant Rhodamine B. The performance of doped ZnO is compared with the pristine ZnO. Scanning electron microscopy (SEM) was used to explore the morphology and it shows nanorod like morphology for all samples and no considerable change in the structural features were found. The dimension of nanorod is 200 to 300 nm. XRD of the fabricated structures showed that ZnO possess hexagonal wurtzite phase. Photo catalytic activity of rhodamine B was investigated under UV light and a maximum degradation efficiency of 85% was obtained. The optical property reveals the reduction in band gap of upto 17.14% for 100 mg Sn doped ZnO. The degradation is followed by the pseudo order kinetics. The produced results are unique in terms of facile synthesis of Sn doped ZnO and excellent photo degradation efficiency, therefore these materials can be used for other environmental applications.

A Low Charge Transfer Resistance CuO Composite for Efficient Oxygen Evolution Reaction in Alkaline Media.

An efficient, simple, environment-friendly and inexpensive cupric oxide (CuO) electrocatalyst for oxygen evolution reaction (OER) is demonstrated. CuO is chemically deposited on the porous carbon material obtained from the dehydration of common sugar. The morphology of CuO on the porous carbon material is plate-like and monoclinic crystalline phase is confirmed by powder X-ray diffraction. The OER activity of CuO nanostructures is investigated in 1 M KOH aqueous solution. To date, the proposed electrocatalyst has the lowest possible potential of 1.49 V versus RHE (reversible hydrogen electrode) to achieve a current density of 20 mA/cm2 among the CuO based electrocatalysts and has Tafel slope of 115 mV dec-1. The electrocatalyst exhibits an excellent long-term stability for 6 hours along with significant durability. The enhanced catalytic active centers of CuO on the carbon material are due to the porous structure of carbon as well as strong coupling between CuO-C. The functionalization of metal oxides or other related nanostructured materials on porous carbon obtained from common sugar provides an opportunity for the development of efficient energy conversion and energy storage systems.

Chemically Coupled Cobalt Oxide Nanosheets Decorated onto the Surface of Multiwall Carbon Nanotubes for Favorable Oxygen Evolution Reaction.

Cobalt oxide has been widely investigated among potential transition metal oxides for the electrochemical energy conversion, storage, and water splitting. However, they have inherently low electronic conductivity and high corrosive nature in alkaline media. Herein, we propose a promising and facile approach to improve the conductivity and charge transport of cobalt oxide Co3O4 through chemical coupling with well-dispersed multiwall carbon nanotubes (MWCNTs) during hydrothermal treatment. The morphology of prepared composite material consisting of nanosheets which are anchored on the MWCNTs as confirmed by scanning electron microscopy (SEM). A cubic crystalline system is exhibited by the cobalt oxide as confirmed by the X-ray diffraction study. The Co, O, and C are the only elements present in the composite material. FTIR study has indicated the successful coupling of cobalt oxide with MWCNTs. The chemically coupled cobalt oxide onto the surface of MWCNTs composite is found highly active towards oxygen evolution reaction (OER) with a low onset potential 1.44 V versus RHE, low overpotential 262 mV at 10 mAcm-2 and small Tafel slope 81 mV dec-1. For continuous operation of 40 hours during durability test, no decay in activity was recorded. Electrochemical impedance study further revealed a low charge transfer resistance of 70.64 Ohms for the composite material during the electrochemical reaction and which strongly favored OER kinetics. This work provides a simple, low cost, and smartly designing electrocatalysts via hydrothermal reaction for the catalysis and energy storage applications.

An Efficient and Functional Fe3O4/Co3O4 Composite for Oxygen Evolution Reaction.

The design of efficient, stable, durable and noble metal free electro catalysts for oxygen evolution reaction (OER) are of immediate need, but very challenging task. In this study, iron induction into cobalt oxide (Co3O4) has resulted composite structure by wet chemical method. The iron impurity has brought an electronic disorder into Fe3O4/cobalt oxide composite thereby efficient oxygen evolution reaction is demonstrated. An addition of iron content into composite resulted the alternation of morphology from Nano rods to clusters of nanoparticles. The successive addition of iron into composite system reduced the onset potential of OER as compared to the pristine cobalt oxide. A Tafel slope of 80 mVdec-1 indicates the favorable oxygen evolution reaction kinetics on the sample 4. An over-potential of 370 mV is required to reach a 10 mAcm-2 current density which is acceptable for a nonprecious catalyst. The catalyst is highly durable and stable for 30 hours. Electrochemical impedance spectroscopy further provided a deeper insight on charge transfer resistance and sample 4 has low charge transfer resistance that supported the OER polarization curves. The sample 4 has more electrochemical active surface area of 393.5 cm². These obtained results are exciting and highlighting the importance of composite structure and leave a huge space for the future investigations on composite materials for energy related applications.

An advanced and efficient Co3O4/C nanocomposite for the oxygen evolution reaction in alkaline media.

The design of efficient nonprecious catalysts for the hydrogen evolution reaction (HER) or the oxygen evolution reaction (OER) is a necessary, but very challenging task to uplift the water-based economy. In this study, we developed a facile approach to produce porous carbon from the dehydration of sucrose and use it for the preparation of nanocomposites with cobalt oxide (Co3O4). The nanocomposites were studied by the powder X-ray diffraction and scanning electron microscopy techniques, and they exhibited the cubic phase of cobalt oxide and porous structure of carbon. The nanocomposites showed significant OER activity in alkaline media, and the current densities of 10 and 20 mA cm-2 could be obtained at 1.49 and 1.51 V versus reversible hydrogen electrode (RHE), respectively. The impedance study confirms favorable OER activity on the surface of the prepared nanocomposites. The nanocomposite is cost-effective and can be capitalized in various energy storage technologies.

Efficient tri-metallic oxides NiCo2O4/CuO for the oxygen evolution reaction.

In this study, a simple approach was used to produce nonprecious, earth abundant, stable and environmentally friendly NiCo2O4/CuO composites for the oxygen evolution reaction (OER) in alkaline media. The nanocomposites were prepared by a low temperature aqueous chemical growth method. The morphology of the nanostructures was changed from nanowires to porous structures with the addition of CuO. The NiCo2O4/CuO composite was loaded onto a glassy carbon electrode by the drop casting method. The addition of CuO into NiCo2O4 led to reduction in the onset potential of the OER. Among the composites, 0.5 grams of CuO anchored with NiCo2O4 (sample 2) demonstrated a low onset potential of 1.46 V vs. a reversible hydrogen electrode (RHE). A current density of 10 mA cm-2 was achieved at an over-potential of 230 mV and sample 2 was found to be durable for 35 hours in alkaline media. Electrochemical impedance spectroscopy (EIS) indicated a small charge transfer resistance of 77.46 ohms for sample 2, which further strengthened the OER polarization curves and indicates the favorable OER kinetics. All of the obtained results could encourage the application of sample 2 in water splitting batteries and other energy related applications.

Facile efficient earth abundant NiO/C composite electrocatalyst for the oxygen evolution reaction.

Due to the increasing energy consumption, designing efficient electrocatalysts for electrochemical water splitting is highly demanded. In this study, we provide a facile approach for the design and fabrication of efficient and stable electrocatalysts through wet chemical methods. The carbon material, obtained by the dehydration of sucrose sugar, provides high surface area for the deposition of NiO nanostructures and the resulting NiO/C catalysts show higher activity towards the OER in alkaline media. During the OER, a composite of NiO with 200 mg C can produce current densities of 10 and 20 mA cm-2 at a bias of 1.45 V and 1.47 V vs. RHE, respectively. Electrochemical impedance spectroscopy experiments showed the lowest charge transfer resistance and the highest double layer capacitance in the case of the NiO/C composite with 200 mg C. The presence of C for the deposition of NiO nanostructures increases the active centers and consequently a robust electrocatalytic activity is achieved. The obtained results in terms of the low overpotential and small Tafel slope of 55 mV dec-1 for non-precious catalysts are clear indications for the significant advancement in the field of electrocatalyst design for water splitting. This composite material based on NiO/C is simple and scalable for widespread use in various applications, especially in supercapacitors and lithium-ion batteries.